Publications
Moldenhauer, J.; Sella, C.; Moffett, B.; Baker, J.; Thouin, L.; Amatore, C.; Kilyanek, S. M.; Paul, D. W. Optimization of Electrochemical Time of Flight Measurements for Precise Determinations of Diffusion Coefficients over a Wide Range in Various Media. Electrochimica Acta 2020, 345, 136113. DOI:10.1016/j.electacta.2020.136113
Tran, R.; Kilyanek, S. M. Deoxydehydration of Polyols Catalyzed by a Molybdenum Dioxo-Complex Supported by a Dianionic ONO Pincer Ligand. Dalton Trans. 2019, 48, 16304. DOI:10.1039/C9DT03759D
Denike, K. A.; Kilyanek, S. M. Deoxydehydration of Vicinal Diols by Homogeneous Catalysts: A Mechanistic Overview. R. Soc. open sci. 2019, 6, 191165. Invited Review DOI:10.1098/rsos.191165
Black, R. E.; Kilyanek, S. M.; Jordan, R. F. Olefin Insertion Reactivity of a (Phosphine-arenesulfonate)Palladium(II) Fluoride Complex. Organometallics 2019, 38, 4250. DOI:10.1021/acs.organomet.9b00545
Thapa, R.; Kilyanek, S. M. Synthesis and Structural Characterization of Iridium(I) Complexes of 20-Membered Macrocyclic Rings Bearing Chelating bis(N-Heterocyclic Carbene) Ligands. Acta Cryst. C 2019, C75, 1652. DOI:10.1107/S2053229619015006
Thapa, R.; Kilyanek, S. M. "Synthesis and Structural Characterization of Nickel(II) Complexes of 20-Membered Macrocyclic Rings Bearing Chelating bis(N-Heterocyclic Carbene) Ligands. J. Organomet. Chem. 2019, 901, 120937. DOI:10.1016/j.jorganchem.2019.120937
Thapa, R.; Kilyanek, S. M. "Synthesis and Structural Characterization of 20-membered Macrocyclic Rings Bearing trans-Chelating bis(N-heterocyclic Carbene) Ligands and the Catalytic Activity of their Palladium(II) Complexes" Dalton Trans. 2019, 48, 12577. DOI: 10.1039/C9DT02147G
Thapa, R.; Kilyanek, S. M. “(2,2-Bi-pyridine-Κ-2N,N')chlorido-[η6-1-methyl-4-(propan-2-yl)benzene]-ruthenium(II) tetra¬phenyl¬borate” IUCrData 2019, 4, x191006. DOI: 10.1107/S241431461901006X
Kilyanek, S. M.; Thapa, R. “N-HETEROCYCLIC CARBENE (NHC) BASED LIGANDS AND RELATED METHODS" U.S. Provisional Patent # 62547253 Aug. 18, 2017, Utility Patent Filing Aug 20, 2018.
Surendranath, Y.; Kilyanek, S. M.; Chu, S. “Fluorinated Coatings for High Performance Electrodes” U.S. Provisional Patent # 62109869. Jan. 30, 2015. Full application Feb. 1, 2016.
Forrest, W. P.; Choudhuri, M. M. R.; Kilyanek, S. M.; Natoli, S. N.; Prentice, B. M.; Fanwick, P. E.; Crutchley, R. J.; Ren, T. “Synthesis and Electronic Structure of Ru2(Xap)4(Y-gem-DEE) Type Compounds: Effect of Cross-Conjugation” Inorg. Chem. 2015, 54, 7645. DOI:10.1021/acs.inorgchem.5b01315
Previous PublicationsTownsend, E. M.; Kilyanek, S. M. Schrock, R. R.; Müller, P.; Smith, S. J.; Hoveyda, A. H. High Oxidation State Molybdenum Imido Heteroatom-Substituted Alkylidene Complexes. Organometallics 2013, 32, 4612.
Flook, M. M.; Börner, J.; Kilyanek, S. M.; Gerber, L. H. C. Schrock, R. R. Five-Coordinate ¸Rearrangements of Metallacyclobutane Intermediates during Ring-Opening Metathesis Polymerization of 2,3-Dicarboalkoxynorbornenes by Molybdenum and Tungsten Monoalkoxide Pyrrolide Initiators. Organometallics 2012, 31, 6231.
Kilyanek, S. M.; Stoebenau, E. J. III; Vinayavekhin, N.; Jordan, R. F., Mechanism of the Reaction of Vinyl Chloride with (a-diimine)Pd-Me+ Species. Organometallics 2010, 29, 1750-1760.
Kilyanek, S. M.; Fang, X. D.; Jordan, R. F., Synthesis and Reactivity of a Tetragallium Macrocycle. Organometallics 2009, 28, 300–305.
Sydora, O. L.; Kilyanek, S. M.; Jordan, R. F., Mechanism of Alkyne Insertion of a Cationic Zirconocene Aryl Complex. J. Am. Chem. Soc. 2007, 129, 12952-12953.
Sydora, O. L.; Kilyanek, S. M.; Jordan, R. F., Cationic Zirconocene and Hafnocene Aryl Complexes, Organometallics 2007, 26, 4746-4755.